Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 67, Issue 17, Pages 6272-6274Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo025960d
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A variety of ketoximes, easily prepared from the corresponding ketones, undergo the Beckmann rearrangement upon treatment with 2,4,6-trichloro[1,3,5]triazine in N,N-dimethylformamide at room temperature in excellent yields. This procedure can be applied to aldoximes for obtaining the corresponding nitriles.
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