4.4 Article

New type chiral calix[4](aza)crowns: synthesis and chiral recognition

Journal

TETRAHEDRON LETTERS
Volume 43, Issue 35, Pages 6249-6253

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(02)01322-9

Keywords

chiral calix[4](aza)crown; synthesis; L-valine; chiral recognition

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Two new types of chiral calix[4](aza)crowns containing L-Valine were synthesized by the reaction of calix[4]arene diacid dichloride with the corresponding chiral diamines derived from C-2-symmetric chiral disulfonamides. Preliminary application of one ligand in chiral recognition was Studied by H-1 and C-13 NMR, and UV spectroscopy. (C) 2002 Elsevier Science Ltd. All rights reserved.

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