Journal
NANO LETTERS
Volume 2, Issue 9, Pages 999-1002Publisher
AMER CHEMICAL SOC
DOI: 10.1021/nl0202105
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Dendrimer-encapsulated Pd(0) nanoparticles inside poly(propylene imine) (PPI) dendrimers functionalized with triethoxybenzamide groups have been prepared by extraction of Pd2+ and subsequent chemical reduction. The resulting dendrimer-Pd nanocomposites are unique catalysts for substrate-specific hydrogenation of polar olefins, due to the strong interaction between polar substrates and tertiary amino groups within the dendrimers.
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