An empirical method for the conversion of spectral UV irradiance measurements to actinic flux data

Routinely monitored radiation parameters, including those at UV wavelengths, most commonly refer to irradiance, that is the radiation incident on a flat horizontal plate. However, in the study of atmospheric chemistry, where UV radiation is a prime photochemical driver, the target molecules are approximately spherical and the actinic flux (radiation on the surface of a sphere) is a better measure of the effective radiation. Unfortunately actinic flux measurements (also known as scalar irradiance) are uncommon research measurements. The ability to convert irradiance data to actinic flux data within a reasonable degree of uncertainty would provide an actinic flux database mapped from existing irradiance databases, thus vastly increasing knowledge of actinic flux variability and climatology. Synchronised spectral UV irradiance and actinic flux measurements have been made during the ADMIRA project, and used to develop an empirical method for converting irradiance to actinic flux. With some prior knowledge of the sky conditions during the irradiance measurements the actinic flux can be estimated to within a few percent. If no knowledge of the sky conditions is available then the empirical method still returns actinic fluxes within 10% of those measured at the site for which the conversion was developed. (C) 2002 Elsevier Science Ltd. All rights reserved.