4.4 Article

Preferential hydrolysis of benzylic/allylic dithianes and dithiolanes using o-iodoxybenzoic acid (IBX) in DMSO containing traces of water

Journal

TETRAHEDRON LETTERS
Volume 43, Issue 36, Pages 6443-6445

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(02)01346-1

Keywords

activated dithianes; activated dithiolanes; selective hydrolysis; IBX

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Dithianes and dithiolanes at benzylic or allylic carbons can easily be hydrolyzed by IBX in DMSO, whereas non-activated dithianes/dithiolanes are much more stable under these conditions. (C) 2002 Elsevier Science Ltd. All rights reserved.

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