4.4 Article

A rapid, two step construction of novel C48H24 and C54H24 polycyclic aromatic hydrocarbons represented on the C60-fullerene surface via a threefold intramolecular Heck coupling reaction

Journal

TETRAHEDRON LETTERS
Volume 43, Issue 37, Pages 6557-6560

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(02)01471-5

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In a new approach towards deeper, higher order 'bucky bowls', two step syntheses of novel polycyclic aromatic hydrocarbons C48H24 and C54H24, having 13 and 16 rings, respectively, from readily available precursors and involving threefold palladium mediated intramolecular Heck coupling as the pivotal step is described. (C) 2002 Published by Elsevier Science Ltd.

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