Journal
ORGANIC LETTERS
Volume 4, Issue 19, Pages 3321-3324Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol026660l
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- NIGMS NIH HHS [GM-61591] Funding Source: Medline
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A rapid, highly efficient and general dynamic kinetic resolution (DKR) of racemic alpha-aryl UNCAs with the dual-function catalysis of modified cinchona alkaloid was accomplished at room temperature. This DKR led to the development of a highly enantioselective catalytic method for the practical synthesis of a wide rang of alpha-aryl and alpha-heteroaryl amino acids in 89-92% ee and 86-95% yield from racemic UNCAs.
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