4.4 Article

Heck reactions in a non-aqueous ionic liquid using silica supported palladium complex catalysts

Journal

TETRAHEDRON LETTERS
Volume 43, Issue 39, Pages 7115-7118

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(02)01320-5

Keywords

Heck reaction; ionic liquid; supported palladium catalyst

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The Heck reaction of iodobenzene and 4-methyl-iodobenzene with olefins using silica-supported palladium complex catalysts was conducted in 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim]PF6), exhibiting higher activities than in DMF in addition to easy product isolation and catalyst recycling. (C) 2002 Elsevier Science Ltd. All rights reserved.

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