Journal
TETRAHEDRON LETTERS
Volume 43, Issue 40, Pages 7267-7270Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(02)01516-2
Keywords
palladium; Suzuki reaction; successive cross-coupling; diarylquinolines
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The conditions for selective stepwise substitution of iodine and chlorine atoms in 4-chloro-6-iodoquinoline which allow the synthesis of the corresponding diarylquinolines with different aryl groups in the 4- and 6-positions, in a one-pot procedure, in high yields are reported. A significant effect of the addition of water or BU4NBr on the rate and yield of both stages was discovered. (C) 2002 Elsevier Science Ltd. All rights reserved.
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