Journal
TETRAHEDRON
Volume 58, Issue 40, Pages 8119-8125Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(02)00912-2
Keywords
polyethers; terpenoids; squalene; marine metabolites
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The red seaweed Laurencia viridis is a rich source of secondary metabolites derived from squalene, Novel polyethers, clavidol 4, 3-epi-1111-dehydrothyrsiferol 5, and lactodehydrothyrsiferol 6, have been isolated and their structures established by spectroscopical methods. The relative steroechemistry proposed for these compounds is based on ROESY and NOEDIFF data. Possible biogenetic pathways are also discussed. (C) 2002 Elsevier Science Ltd. All rights reserved.
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