Journal
ACCOUNTS OF CHEMICAL RESEARCH
Volume 35, Issue 10, Pages 835-846Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ar020001r
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Funding
- NIGMS NIH HHS [GM63167-01A1] Funding Source: Medline
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This Account chronicles the conceptual development, proof of principle, exploration of scope, and mechanistic investigations of a newly developed class of palladium-catalyzed cross-coupling reactions of silicon derivatives. Under the influence of fluoride activation a myriad of oxygen-containing silicon moieties undergo mild and stereospecific cross-coupling. The diversity of methods for introduction of silicon groupings into organic molecules and the range of organic electrophiles that can be used are outlined.
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