New interpenetrating polymer networks based on uralkyd/poly(glycidyl methacrylate)

Semi- and full-interpenetrating polymer networks (IPNs) based on uralkyd resin (UA)/poly(glycidyl methacrylate) were synthesized in the laboratory by the sequential technique. Infrared spectra of the homopolymers and the IPNs were studied. A study of the mechanical properties viz. tensile strength and elongation percentage was carried out. The apparent densities of the homopolymers and their IPNs were determined and compared. Glass transition studies of the IPNs were conducted with the aid of differential scanning calorimetry (DSC). Phase morphology of the IPNs was observed using scanning electron microscopy (SEM). DSC results revealed a single glass transition temperature (T,) for both the semi- as well as the full-IPNs suggesting good interpenetration in them. The SEM micrographs as well as the IR-spectra gave an indication that apart form the interpenetration phenomena, grafting reaction between the -NCO groups of UA and the epoxy group of glycidyl methacrylate might have occurred to some extent. (C) 2002 Elsevier Science Ltd. All rights reserved.