4.5 Article Proceedings Paper

Electronic and geometric structures of metallofullerene peapods

Journal

PHYSICA B-CONDENSED MATTER
Volume 323, Issue 1-4, Pages 97-99

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/S0921-4526(02)00991-2

Keywords

EELS; peapod; Sm-metallofullerenes

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The electronic and geometric structures of the Sm-metallofullerene peapods (Sm@C-82)(n)@SWNTs, are investigated by in situ high-resolution transmission electron microscopy (HRTEM) and electron energy-loss spectroscopy (EELS). The obtained EELS spectra reveal that the encapsulated Sm ion takes +2 state in (Sm@C-82)(n)@SWNTs irrespective of the physical and the electronic properties of single-wall nanotubes. (C) 2002 Elsevier Science B.V. All rights reserved.

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