4.8 Article

C2-symmetric Sc(III)-complexes chiral Lewis acids.: Catalytic enantioselective aldol additions glyoxylate esters

Journal

ORGANIC LETTERS
Volume 4, Issue 20, Pages 3375-3378

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol026488l

Keywords

-

Funding

  1. NIGMS NIH HHS [GM 3328-18] Funding Source: Medline

Ask authors/readers for more resources

[GRAPHICS] Cationic Lewis acid complexes [Sc(pyridyl-bis(oxazolinyl)](Cl-2)SbF6 1a and 1b catalyze aldol reactions with ethyl glyoxylate with enantioselectivities ranging from 90 to 99% ee and syn reaction diastereoselections ranging from 90:10 to 95:5.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.8
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available