Rheological characterization of cellulose solutions in N-methyl morpholine N-oxide monohydrate

Three different modes of rheological properties were measured on 11 and 13 wt% solutions of cellulose in N-methyl morpholine N-oxide (NMMO) monohydrate, in which concentration range lyocell fibers of much reduced fibrillation are preferably produced. The dynamic rheological responses revealed that the Cox-Merz rule did not hold for these cellulose solutions. Both cellulose solutions showed a shear thinning behavior over the shear rate measured at 85, 95, 105, and 115degreesC. However, 13 wt% solution gave rise to yield behavior at 85degreesC. The power law index ranged from 0.36 to 0.58. First normal stress difference (N-1) was increased with lowering temperature and with increasing concentration as expected. Plotting N-1 vs shear stress (T-w) gave almost a master curve independent of temperature and concentration, whose slope was about 0.93 for both cellulose solutions over the shear rate range observed (T-w > 500 Pa). In addition, the cellulose solutions gave high values of recoverable shear strain (S-R), ranging from 60 to 100. (C) 2002 Wiley Periodicals, Inc.