Journal
SCIENCE
Volume 298, Issue 5591, Pages 204-206Publisher
AMER ASSOC ADVANCEMENT SCIENCE
DOI: 10.1126/science.1073338
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The hydrosilylation reaction enables the production of silicon polymers. Platinum-carbene complexes are reported that catalyze the hydrosilylation reaction of alkenes with remarkable efficiency and exquisite selectivity and avoid the formation of platinum colloids. By-products, typically encountered with previous catalytic systems, are suppressed with these platinum derivatives.
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