Journal
POLYHEDRON
Volume 21, Issue 23, Pages 2357-2360Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0277-5387(02)01215-9
Keywords
oxidative addition reaction; perfluoro-n-butyl iodide; 1,5-cyclooctadiene; fluoroalkyls
Categories
Ask authors/readers for more resources
Reaction of (COD)PtMe2 (COD = 1,5-cyclooctadiene) with one molar equivalent of C4F9I in hexanes produces the perfluoroalkylplatinum product (COD)PtMe(C4F9) (1) along with the known Pt(IV) complex [PtMe3I](4). This result stands in contrast to previous reports that attempts to synthesize platinum complexes with fluoroalkyls larger than CF3 gave only inseparable mixtures. An essential condition to the controlled synthesis of 1 is the use of only one equivalent of perfluoroalkyl iodide. Similar reactions reported previously employed an excess of iodoperfluorocarbon, which gave rise to mixtures of products due to successive oxidative addition and reductive elimination reactions. The X-ray crystal structure (COD)PtMe2 was determined. (C) 2002 Elsevier Science Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available