Femtosecond pump-probe reflectivity study of silicon carrier dynamics

We have studied the ultrafast optical response of native-oxide terminated Si(001) with pump-probe reflectivity using 800 nm, 28 fs pulses at an excitation density of (5.5+/-0.3)x10(18) cm(-3). Time-dependent reflectivity changes comprise third-order-response coherent-transient variations arising from anisotropic state filling and linear-response variations arising from excited free carriers, state filling, and lattice heating. A time constant of 32+/-5 fs associated with momentum relaxation is extracted from the coherent-transient variations. The state-filling and free-carrier responses are sensitive to carrier temperature, allowing an electron-phonon energy relaxation time of 260+/-30 fs to be measured. The recovery of the reflectivity signal back towards its initial value is largely governed surface recombination: a surface recombination velocity of (3+/-1)x10(4) cm s(-1) is deduced for native-oxide terminated Si(001).