Journal
JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC
Volume 18, Issue 4-6, Pages 267-272Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S1381-1177(02)00105-4
Keywords
Rhodococcus sp.; optically active; racemic nitriles; nitrile hydratase; amidase; enantioselectivity; 2-methylcyclopropanecarboxylic acid; 2,2-dimethylcyclopropanecarboxylic acid
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Catalyzed by Rhodococcus sp. AJ270 microbial cells under very mild conditions, racemic 2,2-dimethylcyclopropanecarbonitrile (1) and its amide (2), and trans- and cis-2-methylcyclopropanecarboxaniides (4) and (7) underwent enantioselective hydrolysis to give the corresponding optically active amides and acids. (C) 2002 Elsevier Science B.V. All rights reserved.
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