4.4 Article

Should anionised benzylic sulfones be considered as carbenoids?

Journal

TETRAHEDRON LETTERS
Volume 43, Issue 44, Pages 7907-7911

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(02)01908-1

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Na-Hg reduction of benzyl sulfones 1c-e in aprotic solvent conditions affords stilbenes 4c-e, an olefination process best explained by assuming that the corresponding sulfone carbanion, which was formed under these conditions, is decomposed into a carbene species. (C) 2002 Published by Elsevier Science Ltd.

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