Journal
CATALYSIS LETTERS
Volume 83, Issue 3-4, Pages 121-126Publisher
KLUWER ACADEMIC/PLENUM PUBL
DOI: 10.1023/A:1021006718974
Keywords
reverse water gas shift; temperature programmed desorption; Cu/SiO2; formate mechanism
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The mechanism of reverse water gas shift reaction over Cu catalyst was studied by pulse reaction with QMS monitoring, temperature programmed desorption (TPD) and temperature programmed reduction (TPR) of Cu/SiO2 catalyst. The reduced and/or oxidized copper offered low catalytic activity for the dissociation of CO2 to CO in the pulse reaction study with 1 ml volume of He/CO2, but the rate of CO formation was significantly enhanced with H-2 participating in the reaction. The TPD spectra of CO2 obtained by feeding H-2/CO2 over copper at 773 K provided strong evidence of the formation of formate at high temperature. The formate derived from the association of H-2 and CO2 is proposed to be the key intermediate for CO production. The formate dissociation mechanism is the major reaction route for CO production.
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