Journal
CHEMICAL PHYSICS
Volume 284, Issue 1-2, Pages 521-541Publisher
ELSEVIER
DOI: 10.1016/S0301-0104(02)00714-0
Keywords
random walks; stable probability distributions; anomalous diffusion; fractional derivatives; stochastic processes
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A physical-mathematical approach to anomalous diffusion may be based on generalized diffusion equations (containing derivatives of fractional order in space or/and time) and related random walk models. By space-time fractional diffusion equation we mean an evolution equation obtained from the standard linear diffusion equation by replacing the second-order space derivative with a Riesz-Feller derivative of order alpha is an element of (0, 2] and skewness theta (\theta\ less than or equal to, min{alpha,2 - alpha}), and the first-order time derivative with a Caputo derivative of order beta is an element of (0,1]. Such evolution equation implies for the flux a fractional Fick's law which accounts for spatial and temporal non-locality. The fundamental solution (for the Cauchy problem) of the fractional diffusion equation can be interpreted as a probability density evolving in time of a peculiar self-similar stochastic process that we view as a generalized diffusion process. By adopting appropriate finite-difference schemes of solution, we generate models of random walk discrete in space and time suitable for simulating random variables whose spatial probability density evolves in time according to this fractional diffusion equation. (C) 2002 Elsevier Science B.V. All rights reserved.
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