Journal
JOURNAL OF HETEROCYCLIC CHEMISTRY
Volume 39, Issue 6, Pages 1235-1240Publisher
WILEY
DOI: 10.1002/jhet.5570390618
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New chiral pyrazoles, (4R,7R)-4-methyl-7-isopropyl-3-phenyl- (3-phenylisomenthopyrazole; cis-1), (4R,7S)-4-methyl-7-isopropyl- (1-menthopyrazole; trans-2), (4R,7R)-4-isopropyl-7-methyl- (isocarvomenthopyrazole, cis-3) and (4R,7S)-4-isopropyl-7-methyl-4,5,6,7-tetrahydro-1H-indazole (carvomenthopyrazole, trans-3) were prepared. The diastereomeric pairs of these 1-3 were structurally characterized by NMR spectroscopy. The subtle differences of structures of 1-3 should induce the useful effects for a chiral auxiliary or a chiral catalyst.
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