Journal
NANO LETTERS
Volume 2, Issue 11, Pages 1249-1252Publisher
AMER CHEMICAL SOC
DOI: 10.1021/nl025791c
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Single-walled carbon nanotubes (SWNTs) strongly adsorb macrocyclic tetraazaannulene complexes NiTMTAA and CuTMTAA from ethanol solutions, with a SWNT/complex mass ratio of ca. 5:4. According to the results of molecular mechanics modeling, this corresponds to dense monolayer coverage. A saddle-shaped conformation of the macrocyclic complexes facilitates their better accommodation on the cylindrical nanotube walls, resulting in highly ordered molecular arrays.
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