4.4 Article

Homocoupling of alkyl-, alkenyl-, and arylboronic acids

Journal

TETRAHEDRON LETTERS
Volume 43, Issue 45, Pages 8149-8151

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(02)01897-X

Keywords

dimerisation; annulation; chromium; boron; coupling reactions

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Alkyl-, alkenyl-, and arylboronic acids undergo Ag2O/CrCl2, mediated homocoupling in moderate to good yields under mild conditions. The general utility of this methodology is illustrated by an intramolecular annulation between sp and sp(3) centers. (C) 2002 Published by Elsevier Science Ltd.

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