Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 4, Issue 22, Pages 5546-5549Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b206313a
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Rate constants of the electron self-exchange for the TEMPO./TEMPO+ couple were measured in acetonitrile, benzonitrile, deuterium oxide, propylene carbonate, THF and water at T = 298 K. The experimental rate constants cover a range of 0.88 x 10(8) less than or equal to k(et) less than or equal to 5.0 x 10(8) M-1 s(-1) and clearly show a solvent dynamical friction effect controlled by the longitudinal relaxation time of the solvent tau(L).
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