Journal
TETRAHEDRON LETTERS
Volume 43, Issue 47, Pages 8611-8615Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(02)01895-6
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An alkanoylpyrene moiety was used as a principal chromophore for labeling photoactive amphipathic polypeptides with a high propensity for self-assembly. Electrochemical, emission and transient absorption data showed that photoinduced electron transfer within pairs of pyrene pendants accounts for a lower fluorescence quantum yield observed for aggregated chromophores and for the formation of radical-ion, intermediates. (C) 2002 Elsevier Science Ltd. All rights reserved.
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