Journal
ORGANIC LETTERS
Volume 4, Issue 24, Pages 4321-4323Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0269603
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graphic Multifunctional palladium catalysis is utilized in the one-pot stereocontrolled synthesis of tetrasubstituted methyl ketones and enynes. The homogeneous palladium dihalide catalyst utilized for the bromo-/chloroallylation of alkynes is reused in situ for subsequent Wacker-Tsuji oxidation or Sonogashira cross-coupling.
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