Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 67, Issue 24, Pages 8685-8687Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo0203701
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A Cp*Rh(III) complex catalyzes reductive amination of ketones using HCOONH4 at 50-70 degreesC to give the corresponding primary amines in high yields. The reaction is clean and operationally simple and proceeds at a lower temperature and with higher chemoselectivity than the original Leuckart-Wallach reaction. The new method has been applied to the synthesis of alpha-amino acids directly from alpha-keto acids.
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