Journal
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY
Volume 15, Issue 12, Pages 790-795Publisher
JOHN WILEY & SONS LTD
DOI: 10.1002/poc.543
Keywords
binary solvent mixtures; NMR spectroscopy; NOESY; preferential solvation
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The solvation of some neutral and charged organic molecules (phenol, nitroanilines, tetraalkylammonium) in binary solvent mixtures was investigated by means of intermolecular H-1-NOESY NMR spectroscopy. The solvation shell of the solute is, in most cases, selectively enriched in one of the cosolvents (preferential solvation). The origin of preferential solvation is discussed in terms of solute-solvent interactions and microheterogeneity in the solvent mixture. Copyright (C) 2002 John Wiley Sons, Ltd.
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