Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 663, Issue 1-2, Pages 5-12Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-328X(02)01728-X
Keywords
adaptable coordination modes; conjugated 1,3-diene; s-trans coordination
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We briefly describe the unique coordination mode of s-trans-1,3-diene complexes in this review. Since the first discovery of mononuclear s-trans-1,3-diene complexes of zirconocene and hafnocene, this unique coordination mode has been found for a wide variety of transition metals over the Periodic Table. Herein we summarize general aspects of the mononuclear s-trans diene complexes including the recent results, and also describe dinuclear and multinuclear complexes that coordinate in an s-trans fashion to polyenes. (C) 2002 Elsevier Science B.V. All rights reserved.
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