4.4 Article

A synthetic use of the intramolecular alkyl migration process in indolylborates for intramolecular cyclization: a novel construction of carbazole derivatives

Journal

TETRAHEDRON
Volume 58, Issue 49, Pages 9827-9838

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(02)01293-0

Keywords

indolylborate; intramolecular alkyl migration; palladium catalyst; carbazoles

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The intramolecular alkyl migration reaction in indolylborates was developed for the one-pot construction of carbazoles via intramolecular cyclization in which pi-allylpallidium complexes were successfully adopted as an acceptor for the indole nucleophile. (C) 2002 Elsevier Science Ltd. All rights reserved.

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