4.8 Article

Simple approach for charge renormalization in highly charged macroions

Journal

PHYSICAL REVIEW LETTERS
Volume 89, Issue 24, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.89.248301

Keywords

-

Ask authors/readers for more resources

We revisit the notion of renormalized charge, which is a concept of central importance in the field of highly charged colloidal or polyelectrolyte solutions. Working at the level of a linear Debye-Huckel-like theory only, we propose a versatile method to predict the saturated amount of charge renormalization, which is, however, a nonlinear effect arising at strong electrostatic coupling. The results are successfully tested against nonlinear Poisson-Boltzmann theory for polyions of various shapes (planar, cylindrical, and spherical), both in the infinite dilution limit or in confined geometry, with or without added electrolyte. Our approach, accurate for monovalent microions in solvents such as water, is finally confronted against experimental results on charged colloids and B-DNA solutions.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.8
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available