Journal
ORGANIC LETTERS
Volume 4, Issue 25, Pages 4491-4494Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol027003w
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[GRAPHICS] We have developed a new method that affords regioisomerically pure corroles possessing up to three different substituents at the meso positions. The corrole formation reaction involves the acid-catalyzed condensation of a dipyrromethane-dicarbinol with pyrrole followed by oxidation with DDQ. ABC-Type corroles were synthesized for the first time according to this procedure.
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