☆ 4.4 Article

The mechanism of the tertiary amine catalysed isomerisation of endoperoxides to hydroxyketones: synthesis and chemistry of the intermediate postulated in the peroxide attack mechanism

TETRAHEDRON LETTERS (2002)

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Journal

TETRAHEDRON LETTERS
Volume 43, Issue 51, Pages 9331-9333

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(02)02374-2

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Categories

Chemistry, Organic

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Evidence is presented which demonstrates that the Kornblum-DeLaMare rearrangement does not proceed via nucleophilic attack of the peroxide linkage. (C) 2002 Elsevier Science Ltd. All rights reserved.

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