Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 664, Issue 1-2, Pages 298-305Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-328X(02)02026-0
Keywords
samarium; lanthanide; manganese; formate; pyrazolylborate; hydrolysis
Categories
Ask authors/readers for more resources
The reaction of [Sm(Tp(Me2))(2)] with Mn2CO10 results in the reductive cleavage of the Mn-Mn bond and the formation of the salt [Sm(Tp(Me2))(2)]Mn(CO)(5) which has been characterized by X-ray diffraction (Tp(Me2) = HB(3,5-dimethylpyrazolyl)(3)). In addition a second product, [(Tp(Me2))(2)Sm(mu-O2CH)Sm(Tp(Me2))(2)]Mn(CO)(5), was isolated and characterized crystallographically. Two mechanisms for the formation of this complex are proposed. (C) 2002 Elsevier Science B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available