Journal
MACROMOLECULES
Volume 35, Issue 26, Pages 9756-9762Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ma0212700
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Filled elastomers exhibit a complex dependence of their viscoelastic modulus as a function of both temperature and frequency. Otherwise, recent observations on thin polymer films have shown that their glass transition temperature depends on their thickness. On the basis of these recent results and on a recent model, we propose that the mechanical behavior of the filled elastomer is strongly influenced by a gradient of the glass transition temperature in the vicinity of to particles. This allows us to suggest a specific temperature-frequency superposition law far filled rubbers. This law seems apply very successfully on two systems with different dispersion qualities, revealing the existence of a glass transition temperature gradient in the vicinity of the particles.
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