Journal
JOURNAL OF MOLECULAR STRUCTURE
Volume 643, Issue 1-3, Pages 29-35Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S0022-2860(02)00315-0
Keywords
water; H-bonds; co-operativity; infrared spectra; donor numbers; organic solvents
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The co-operativity of water hydrogen bonds has been discussed, as a key to the appropriate interpretation of water infrared spectra. In that respect, interaction energy values have been ascribed to some structural arrangements of water. A scale for water electron donor. properties in aprotic solvents has been proposed, basing on Gutmann's donor numbers. (C) 2002 Elsevier Science B.V. All rights reserved.
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