4.4 Letter

Fabrication of polysilane-titania hybrid thin films

Journal

THIN SOLID FILMS
Volume 422, Issue 1-2, Pages 4-7

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/S0040-6090(02)00776-9

Keywords

polymers; titanium oxide; nanostructures; atomic force microscope

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Poly(methylphenylsilane) (PMPS)/3-methacryloxypropyltriethoxysilane (MPTES) block copolymer (P(MPS-co-MPTES)) has been applied to formation of polysilane-titania hybrid thin film via sol-gel reaction. We have successfully prepared a homogeneous and transparent polysilane-titania hybrid thin film with higher photo-durability than polysilane or polysilane-silica hybrid thin film. The surface of the polysilane-titania hybrid thin film had numerous unevenness approximately 10-20 nm a few hundred nm intervals after UV irradiation. (C) 2002 Elsevier Science B.V. All rights reserved.

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