Journal
TETRAHEDRON LETTERS
Volume 43, Issue 52, Pages 9539-9543Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(02)02416-4
Keywords
phase-transfer catalysis; asymmetric two-center catalyst; alkylation; Michael addition
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A new asymmetric two-center phase-transfer catalyst was designed and a catalyst library containing more than 40 new two-center catalysts was constructed. The catalysts were applied in phase-transfer alkylations and Michael additions to afford the corresponding products in up to 93% ee and 82% ee, respectively. (C) 2002 Elsevier Science Ltd. All rights reserved.
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