Journal
INORGANICA CHIMICA ACTA
Volume 342, Issue -, Pages 301-304Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0020-1693(02)01145-3
Keywords
aziridines; catalysis; iron compounds; nitrenes
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The iron Lewis acid catalyst, [(eta(5)-C5H5)Fe(CO)(2)(THF)](+)[BF4](-), has previously been found to catalyze a growing array of synthetic transformations. Building upon these precedents, the utility of the catalyst has now been extended to catalytic reaction involving olefins and (N-(p -tosyl)imino)phenyliodinane, PhI = NTs, which serves as a nitrenoid precursor, to produce aziridines with yields up to 85%. (C) 2002 Elsevier Science B.V. All rights reserved.
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