4.4 Article

Cyclisation of dienes using phosphorus-centred radicals to form organophosphorus adducts

Journal

TETRAHEDRON LETTERS
Volume 44, Issue 3, Pages 479-483

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(02)02610-2

Keywords

cyclisation; dienes; phosphorus compounds; radicals and radical reactions

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Reaction of various dienes with phosphites or related phosphorus hydrides, under free radical cyclisation conditions, affords cyclic organophosphorus adducts. This quick, mild and technically clean approach affords 5- and 6-ring carbocycles and heterocycles in good to excellent yield. (C) 2002 Elsevier Science Ltd. All rights reserved.

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