Journal
TETRAHEDRON LETTERS
Volume 44, Issue 3, Pages 523-525Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(02)02587-X
Keywords
enantiopure cyclic nitrone; dipolar cycloaddition; facial selectivity
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A new enantiopure cyclic nitrone has been efficiently synthesized from a D-glyceraldehyde derivative. It's 1,3-dipolar cycloaddition to different classes of dipolarophiles show complete antifacial selectivity, furnishing highly functionalized enantiopure bicyclic isoxazolidines. (C) 2002 Elsevier Science Ltd. All rights reserved.
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