Journal
TETRAHEDRON LETTERS
Volume 44, Issue 4, Pages 721-724Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(02)02707-7
Keywords
asymmetric induction; asymmetric synthesis; addition reactions; asymmetric autocatalysis; silica
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Highly enantiomerically enriched (up to 96-97% ee) 5-pyrimidyl alkanol was obtained by the addition of diisopropylzinc to pyrimidine-5-carbaldehyde in the presence of the artificially designed chiral inorganic material, right- and left-handed helical silica. (C) 2003 Elsevier Science Ltd. All rights reserved.
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