4.6 Article

Hybrid organic-inorganic nanocomposite materials for application in solid state electrochemical supercapacitors

Journal

ELECTROCHEMISTRY COMMUNICATIONS
Volume 5, Issue 2, Pages 149-153

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/S1388-2481(03)00010-9

Keywords

hybrid organic-inorganic materials; polyoxometalates; nanosized oxide clusters; phosphomolybdic acid; conducting polymer; polyaniline; polybenzimidazole; proton-conducting membrane; faradaic redox supercapacitor

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Integration into a conducting polymer matrix to form a hybrid material is an effective way to harness the electrochemical activity of nanosized oxide clusters. By anchoring them into polyaniline, the reversible redox chemistry of the otherwise soluble polyoxometalate clusters can be combined with that of the conducting polymer and be put to work in energy storage applications. We present here preliminary results that show how the resulting hybrid polymer displays the combined activity of its organic and inorganic components to store and release charge in a solid state electrochemical capacitor device. (C) 2003 Elsevier Science B.V. All rights reserved.

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