Journal
ACCOUNTS OF CHEMICAL RESEARCH
Volume 36, Issue 2, Pages 140-146Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ar020148i
Keywords
-
Categories
Ask authors/readers for more resources
The activation of alkane C-H bonds by oxidative addition and its reverse reaction, reductive elimination, are believed to occur via transient a-alkane complexes. This Account summarizes how isotope effects can be used to probe the nature of these intermediates and points out some pitfalls in interpreting kinetic data. Comparisons are made with arene C-H activation and other activation systems.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available