Journal
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
Volume 33, Issue 2, Pages 343-358Publisher
TAYLOR & FRANCIS INC
DOI: 10.1081/SIM-120017791
Keywords
curcuminoids; 1,7-diarylheptanoids; metal chelates; antitumour activity; NMR spectra; mass spectra
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Four new curcuminoid (1,7-diaryl-1,6-heptadiene-3,5-diones) analogues and their vanadyl(IV), cobalt(II), nickel(II) and copper(II) chelates of ML2 stoichiometry have been synthesized and characterized by electronic, IR, H-1 NMR, ESR and mass spectral data. The in vitro and in vivo antitumour activity of these 1,7-diarylheptanoids and their copper(II) chelates showed that chelation remarkably enhanced cytotoxic activity and other antitumour properties.
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