3.8 Article

Time evolution in the Morse potential using supersymmetry:: Dissociation of the NO molecule

Journal

EUROPHYSICS LETTERS
Volume 61, Issue 4, Pages 445-451

Publisher

EDP SCIENCES S A
DOI: 10.1209/epl/i2003-00328-9

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W present a new algebraic method for treating molecular vibrations in the Morse potential perturbed by an external field. W introduce a discrete normalizable basis, allowing to expand the dissociated states, as well. The Morse Hamiltonian is particularly simple in this basis, and the matrix elements of a realistic molecular dipole moment operator can also be expressed analytically. As a demonstration, we apply our method to calculate the dissociation probability of the NO molecule excited by appropriate series of chirped laser pulses.

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