Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 41, Issue 3, Pages 365-375Publisher
WILEY
DOI: 10.1002/pola.10567
Keywords
reversible addition-fragmentation chain transfer (RAFT); living free-radical polymerization; block copolymers; kinetics (polym.); supramolecular structures
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This highlight describes recent developments in reversible addition-fragmentation transfer (RAFT) polymerization. Succinct coverage of the RAFT mechanism is supplemented by details of synthetic methodologies for making a wide range of architectures ranging from stars to combs, microgels, and blocks. In addition, RAFT reactions in different media such as emulsion and ionic liquids receive attention. Finally, a specific example of a novel material design is briefly introduced, whereas polymers prepared via RAFT are adopted for microporous/honeycomb membrane design. (C) 2002 Wiley Periodicals, Inc.
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