Journal
MONATSHEFTE FUR CHEMIE
Volume 134, Issue 2, Pages 199-216Publisher
SPRINGER WIEN
DOI: 10.1007/s00706-002-0489-4
Keywords
spin crossover; domain model; solution model; statistical model; cooperativeness
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The existing models of the low-spin to high-spin transition (spin crossover) are briefly reviewed. Experimental data pointing to a need of new models are displayed. A statistical model with the distribution of the solid-state cooperativeness is outlined. A modeling is shown as well as its application to a spin crossover system [Fe(bzimpy)(2)](ClO4)(2) (.) 0.25H(2)O. This shows an abrupt spin crossover at temperature as high as 403 K with a hysteresis width of 12 K. The angled walls of the hysteresis loop can be followed by the outlined statistical model.
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